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santonic acid
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Santonic acid is an organic compound containing both carboxylic acid and ketone functionality.
It was synthesized from santonin by base-mediated hydrolysis of a lactone followed by a multistep rearrangement process by R. B. Woodward.〔Reusch, William (1999). "(Base-catalyzed rearrangements )". In: ''Virtual Textbook of Organic Chemistry''. Michigan State University. Retrieved September 10, 2008.〕
Unusually for a carboxylic acid, santonic acid does not form hydrogen-bonded dimers in the crystalline phase. Rather, it adopts a polymeric structure, with individual santonic acid molecules linked by intermolecular carboxyl-to-ketone hydrogen bonds.〔
==References==
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